Thorium

Thorium (Th)

Introduction

Thorium is a chemical element with the atomic number 90 in the periodic table. The average concentration of this substance in the upper crust of Earth amounts to 10.5 ppm, while thorium concentration in the middle layer (the mantle) is around 6.5 ppm. The core (lowest layer) of the Earth’s crust contains 1.2 ppm on average. 

 

Being a member of the actinide family of periodic table elements, this naturally occurring radioactive metal has four valence electrons. Its most important use is in nuclear power plants as a nuclear fuel. Due to its radioactivity, thorium is classified as a carcinogen substance.

Fact Box

Chemical and Physical Properties of Thorium

The symbol in the periodic table of elements: Th

Atomic number: 90

Atomic weight (mass): 232.04 g.mol-1

Group number: Actinides

Period: 7 (f-block)

Color: A silvery-white lustrous metal

Physical state: Solid at 20°C

Half-life: From 1.7(+1.7-0.6) microseconds to 1.405(6)×1010 years

Electronegativity according to Pauling: 1.3

Density: 11.7 g.cm-3

Melting point: 1750°C, 3182°F, 2023 K

Boiling point: 4785°C, 8645°F, 5058 K

Van der Waals radius: 0.182 nm

Ionic radius: 0.110 nm (+4)

Isotopes: 31

Most characteristic isotope:230Th, 232Th

Electronic shell: [Rn] 6d27s2

The energy of the first ionization: 1107.6 kJ.mol-1

The energy of the second ionization: 1962.4 kJ.mol-1

The energy of the third ionization: 2774 kJ.mol-1

Discovery date: In 1829 by Jöns Jacob Berzelius

 

Classified in the periodic table under the symbol Th, atomic number 90, atomic mass of 232.04 g.mol-1, and electron configuration [Rn] 6d27s2, thorium is a silvery-white, soft and ductile, naturally occurring radioactive metal. 

 

reaches its boiling point at 4785°C, 8645°F, 5058 K, while the melting point is achieved at 1750°C, 3182°F, 2023 K. This member of the actinide family of elements in the periodic table has an electronegativity of 1.3 according to Pauling, whereas the atomic radius according to van der Waals is 0.182 nm.

 

Thorium has a dimorphic structure. It changes from face-centered cubic to body-centered cubic at above 1360oC. With a melting point of 3300°C, thorium oxide melts at the highest temperature among all oxides. Only tungsten, tantalum carbide, and a few other compounds have a higher melting point than element 90.                     

How Was Thorium Discovered?

After receiving a mineral sample from Hans Esmark, obtained from an island close to Brevik, Norway, the Swedish chemist Jöns Jacob Berzelius (1779 – 1848) embarked on studying the unusual black substance that he labeled as thorite

 

After successfully identifying iron, manganese, lead, tin, and uranium in the mineral, Berzelius observed another unfamiliar substance. In 1828, the scientist concluded that there is 57.91% of an oxide of the assumed new element contained in the black thorite mineral. Berzelius named this reactive substance thorium

 

Attempting to isolate the elemental form of the new element, Berzelius triggered a chemical reaction. First, he produced thorium chloride by mixing thorium oxide with carbon. In the next step, the discoverer heated it in a stream of chlorine gas. After this, Berzelius reacted thorium chloride with potassium and got thorium and potassium chloride as a result. 

 

In 1898, both the German organic chemist and chemical crystallographer Gerhard Schmidt (1919–1971) and the first female scientist to win the Nobel prize Marie Curie (1867–1934) independently discovered the radioactive properties of thorium. 

How Did Thorium Get Its Name?

Thorium is named after Thor, the Scandinavian god of thunder, lightning, and war. According to the legend, the Norse God was known for his quick and volatile outbursts of anger, always ready to fight. This relates to the high chemical reactivity and the volatile reactions of element 90. 

Where Can You Find Thorium?

Element 90 is a naturally occurring radioactive metal. Natural thorium can be found in the soil, rocks, fossil fuels, water, plants, and animals. Thorite and thorianite are minerals in which this radioactive metal mostly occurs. It can also be found in thorium silicate, monazite, etc. The metal allotrope of this chemical element is also found in minerals such as titanite, betafite, gadolinite, and zircon.

 

Thorium is so frequently occurring in nature, that the mining locations rich in this substance can be found all over the Globe, in all continents. However, the largest quantities thorium reserves originate from the mines in Australia, the United States, Russia, Canada, and India. 

 

Extraction of thorium as a byproduct of rare-earth elements (REE), as well as isolation of this chemical element from the monazite ore is the most feasible source of thorium production. For commercial purposes, thorium is also obtained by the methods of electrolysis, extraction, and decomposition with sodium hydroxide. 

 

The world’s first thorium molten salt reactor (TMSR) experiment, after the initial experiment at the Oak Ridge National Laboratory (ORNL) during the 1960s, was conducted by the scientists at the Nuclear Research and Consultancy Group (NRG) in Petten, Netherlands. The Salt Irradiation Experiment, or SALIENT, has been prepared in collaboration with the European Commission Laboratory Joint Research Center-ITU, Karlsruhe. Currently, only China, India and Indonesia are included in this project

List of Thorium Minerals

The list of minerals from which thorium can be isolated also contains the items:


  • Aeschynite-(Y)
  • Althupite
  • Aspedamite
  • Auerlite
  • Cheralite
  • Cleveite
  • Ekanite
  • Euxenite
  • Grayite
  • Huttonite
  • Ichnusaite
  • Monazite
  • Nuragheite
  • Polycrase
  • Steacyite
  • Thorianite
  • Thorite
  • Yttrialite
  • Zirkelite

 

Thorium in Everyday Life

Thorium’s physical and chemical properties can be used in a variety of ways which are beneficial for our everyday life:

 

  • As more quantities of thorium are being made available, element 90 is researched as a uranium substitute in nuclear reactors for the production of fuel that generates nuclear energy;
  • Thorium used to be applied in the manufacturing of carbon arc lamps, as well as in mantles of gas lights for that emit intense white light;
  • Thorium dioxide (ThO2) is used as a control mechanism for small amounts of plutonium and tungsten applied in the production process of the metal spirals in electric lamps;
  • When added to glass, thorium improves its refractive index and decreases dispersion. The thorium-enriched glass is used in the manufacturing of camera lenses and scientific equipment. Over time, this type of glass gets a slightly yellow tint, but can be cleared again by exposure to high levels of UV light. The health risks of using lenses made with thorium dioxide are minimal;
  • Element 90 is often used in radiometric dating of fossils, seabeds and mountain ranges;
  • The gaseous form of element 90 (thoria) is used in arc welding for improvement of its strength and stability;
  • In the Mg-Th alloy, tungsten is used along with magnesium metal to increase both creep resistance and strength of the parts used in aircraft engines and rockets;
  • Crucibles, scientific instruments, and heat-resistant ceramic owe their resistance to high temperatures to thorium dioxide as one of the main components;
  • This chemical element is also one of the catalyst agents that participates in the production of sulphuric acid, as well as in the conversion of ammonia to nitric acid in petroleum cracking;
  • Uranium-233 isotopes can be used in nuclear weapons or for making a nuke;
  • The filaments of magnetron tubes which are used to generate microwave frequencies contain traces of thorium;
  • Thorium is also used in gas mantles that produce light in gas lamps;
  • Until the 1950s, thorium dioxide was used in medical radiology as a contrast agent (under the label Thorotrast) for making diagnostic X-ray images. It has been discontinued after the studies have related thorium exposure of the patients to the increased risk of liver tumors;
  • Thorium fluoride gives the antireflection properties of the optical coatings.

How Dangerous Is Thorium?

Thorium metal dust possesses high pyrophoricity that increases the risk of fire and explosion. It’s able to ignite spontaneously when exposed to air and burns brilliantly with a white light.

Thorium Toxicity

Exposure to thorium may occur in several ways:

 

  • Inhalation; 
  • Intravenous injection; 
  • Ingestion (via contaminated water or food);
  • Absorption through the skin. 

 

Initially, the affected individual may experience symptoms such as:

 

  • Eye irritation;
  • Skin irritation;
  • Nausea and vomiting;
  • Headaches;
  • Dermatitis;
  • Bronchospasms;
  • Severe bouts of cough;
  • ARTI (Acute Respiratory Tract Infection);
  • Blood disorders.

 

Prolonged exposure to high levels of thorium can be lethal. In the human body, element 90 typically absorbs in the bones, as well as in the soft tissues and organs. As a consequence, liver, bone, and pancreatitis cancers may develop in individuals exposed to high levels of this carcinogen substance. 

Environmental Effects of Thorium

Despite being one of the most frequently occurring chemical elements in nature, this carcinogen substance is not hazardous to the health of the biological, geological, and aquatic systems in the environment. This is mostly due to the fact that exposure to high levels of this radioactive substance may occur only near the thorium-mining areas and the factories that work with thorium or nuclear waste. 

 

Also, thorium radioactive waste takes more than 500 years to biodegrade. During this period, it poses an environmental threat due to its radioactivity. 

Isotopes of Thorium

Element 90 has 31 observed forms. Among them, seven are naturally occurring isotopes. Since thorium is a radioactive substance, all its isotopes are unstable. While most of the thorium radioisotopes have a half-life of several microseconds to several minutes, the 232Th isotope has a half-life of 1.405(6)×1010 years. 

The Thorium Cycle

Thorium reactors are based on the thorium fuel cycle that uses the thorium-232 isotope as a fertile material. In the thorium cycle of reactions, the thorium-232 isotope can be transformed by thermal neutrons to a fissionable uranium-233 isotope. 

 

The uranium-233 isotope is fissile on its own, i.e. the fission of this form of thorium can provide neutrons for a new thorium cycle. Th-232 isotopes produce Th-233 which undergoes a beta-decay mode (in 22 minutes of half-life) to protactinium-233. The protactinium isotope further decays to uranium-233 by undergoing a beta decay. This parallels the uranium fuel cycle in fast breeder reactors. 

 

The described chain reaction sequence can be observed from the following nuclear reactions:

 

232Th + n ⇒ 233Th

ß decay       ß decay

233Th ⇒    233Pa ⇒     233U

It has been observed that when the uranium-235 content burns down to nearly 0.3%, the highly radioactive residue of the fuel contains radioactive isotopes of iodine, plutonium, americium, and technetium. During the Cold War, the United States had reportedly produced about 2 tonnes of uranium-233 from thorium in plutonium production reactors. 

 

Nuclide

[n 1]

Historic

name

Z N Isotopic mass (Da)

[n 2][n 3]

Half-life

[n 4]

Decay

mode

[n 5]

Daughter

isotope

[n 6]

Spin and

parity

[n 7][n 8]

Natural abundance (mole fraction)
Excitation energy Normal proportion Range of variation
208Th[7] 90 118 208.01791(4) 1.7(+1.7-0.6) ms α 204Ra 0+
209Th[8] 90 119 209.01772(11) 7(5) ms

[3.8(+69−15)]

α 205Ra 5/2−#
210Th 90 120 210.015075(27) 17(11) ms

[9(+17−4) ms]

α 206Ra 0+
β+ (rare) 210Ac
211Th 90 121 211.01493(8) 48(20) ms

[0.04(+3−1) s]

α 207Ra 5/2−#
β+ (rare) 211Ac
212Th 90 122 212.01298(2) 36(15) ms

[30(+20-10) ms]

α (99.7%) 208Ra 0+
β+ (.3%) 212Ac
213Th 90 123 213.01301(8) 140(25) ms α 209Ra 5/2−#
β+ (rare) 213Ac
214Th 90 124 214.011500(18) 100(25) ms α 210Ra 0+
215Th 90 125 215.011730(29) 1.2(2) s α 211Ra (1/2−)
216Th 90 126 216.011062(14) 26.8(3) ms α (99.99%) 212Ra 0+
β+ (.006%) 216Ac
217Th 90 127 217.013114(22) 240(5) μs α 213Ra (9/2+)
218Th 90 128 218.013284(14) 109(13) ns α 214Ra 0+
219Th 90 129 219.01554(5) 1.05(3) μs α 215Ra 9/2+#
β+ (10−7%) 219Ac
220Th 90 130 220.015748(24) 9.7(6) μs α 216Ra 0+
EC (2×10−7%) 220Ac
221Th 90 131 221.018184(10) 1.73(3) ms α 217Ra (7/2+)
222Th 90 132 222.018468(13) 2.237(13) ms α 218Ra 0+
EC (1.3×10−8%) 222Ac
223Th 90 133 223.020811(10) 0.60(2) s α 219Ra (5/2)+
224Th 90 134 224.021467(12) 1.05(2) s α 220Ra 0+
β+β+ (rare) 224Ra
CD 208Pb

16O

225Th 90 135 225.023951(5) 8.72(4) min α (90%) 221Ra (3/2)+
EC (10%) 225Ac
226Th 90 136 226.024903(5) 30.57(10) min α 222Ra 0+
227Th Radioactinium 90 137 227.0277041(27) 18.68(9) d α 223Ra 1/2+ Trace[n 9]
228Th Radiothorium 90 138 228.0287411(24) 1.9116(16) y α 224Ra 0+ Trace[n 10]
CD (1.3×10−11%) 208Pb

20O

229Th 90 139 229.031762(3) 7.34(16)×103 y α 225Ra 5/2+ Trace[n 11]
230Th[n 12] Ionium 90 140 230.0331338(19) 7.538(30)×104 y α 226Ra 0+ 0.0002(2)[n 13]
CD (5.6×10−11%) 206Hg

24Ne

SF (5×10−11%) (Various)
231Th Uranium Y 90 141 231.0363043(19) 25.52(1) h β 231Pa 5/2+ Trace[n 9]
α (10−8%) 227Ra
232Th[n 14] Thorium 90 142 232.0380553(21) 1.405(6)×1010 y α 228Ra 0+ 0.9998(2)
ββ (rare) 232U
SF (1.1×10−9%) (various)
CD (2.78×10−10%) 182Yb

26Ne

24Ne

233Th 90 143 233.0415818(21) 21.83(4) min β 233Pa 1/2+
234Th Uranium X1 90 144 234.043601(4) 24.10(3) d β 234mPa 0+ Trace[n 13]
235Th 90 145 235.04751(5) 7.2(1) min β 235Pa (1/2+)#
236Th 90 146 236.04987(21)# 37.5(2) min β 236Pa 0+
237Th 90 147 237.05389(39)# 4.8(5) min β 237Pa 5/2+#
238Th 90 148 238.0565(3)# 9.4(20) min β 238Pa 0+

Source: Wikipedia

 

List of Thorium Compounds 

There are four outer shell electrons of thorium. All valence electrons of this highly reactive and electropositive element are able to participate in a chemical compound. It readily reacts with oxygen, hydrogen, nitrogen, the halogen elements, and sulfur, when exposed to high temperatures. With phosphorus and carbon, thorium forms binary compounds. 

 

Out of the many compounds prepared with thorium, the following are most common:


  • Thorium dioxide
  • Thorium monoxide
  • Thorium oxalate
  • Thorium tetrafluoride
  • Thorium(IV) carbide
  • Thorium(IV) chloride
  • Thorium(IV) hydroxide
  • Thorium(IV) iodide
  • Thorium(IV) nitrate
  • Thorium(IV) orthosilicate
  • Thorium(IV) sulfide
  • Thorocene

5 Interesting Facts and Explanations

  1. Thorium and uranium are not only the most stable actinides but also the only members of the actinide group of the periodic table that can be safely studied in a regular laboratory.
  2. The substances that spontaneously ignite upon exposure to air at or below 54°C(129 °F) or shortly after being exposed to air are referred to as pyrophoric substances (from the Greek word ‘πυρφόρος / pyrophorus’, meaning ‘fire-bearing’).
  3. In 2011, the China Academy of Sciences launched an R&D program on LFTR. Liquid fluoride thorium reactors (LFTR) produce less waste during the production energy than the reactors powered by uranium. As a comparison, a traditional pressurised water reactor (PWR) would need to burn 250 tonnes of uranium to produce the same amount of energy. Also, no solid fuel rods (or chemical reprocessing) are needed because LFTRs use thorium in its natural state. 
  4. This process of isolating an element from its ore used by the discoverer of thorium was a very familiar one to Berzelius’ fellow chemists. Namely, Ørsted isolated aluminum by the same method in 1825, while in 1828 Wöhler and Bussy succeeded in isolating beryllium in the same way.
  5. Thorium is the second naturally occurring element that has been identified as a radioactive substance, after uranium.