Actinium

Introduction

Actinium is a rare-earth element that belongs to the family of actinides in the periodic table. The actinide series of elements is highly significant due to their radioactive properties. They comprise a group of 15 chemical elements that share the same chemical and physical properties. 

 

Fact Box

Physical and Chemical Properties of Actinium

The symbol in the periodic table of elements: Ac

Atomic number: 89

Atomic weight (mass): 227 g.mol -1

Group number: 3

Period: 7

Color: Silvery-white 

Physical state: A radioactive metal

Electronegativity according to Pauling: 1.1

Density: 10.07 g.cm-3 at 20°C

Melting point: 1050 °C

Boiling point: 3250 °C

Van der Waals radius: Unknown

Ionic radius: Unknown

Isotopes: 4

Electronic shell: [ Rn ] 6d1 7s2

The energy of first ionization: 664.6 kJ.mol -1

The energy of second ionization: 1165.5 kJ.mol -1

Discovery date: In 1899 (1902), by André Debierne

With the periodic table symbol Ac, atomic number 89, atomic mass of 227 g.mol -1, and electronic configuration [Rn] 6d17s2, actinium reaches its boiling point at 3250 °C, while the melting point is achieved at 1050 °C. This member of the actinide family of elements in the periodic table has an electronegativity of 1.1 according to Pauling, whereas the atomic radius according to van der Waals is unknown. 

Actinium displays an oxidation state of +3, which is a chemical property related to lanthanum. The powerful radioactive properties of actinium give this element its most notable physical characteristic – the pale blue glow in the dark. But, it’s not the substance that emits the blue light. 

Since actinium is way more radioactive than radium, it emits an enormous quantity of electrons that stimulate oxygen molecules in the surrounding air. The energy released by the ionized oxygen appears as a pale blue glow from the radioactive substance.  

 

How Was Actinium Discovered?

The French chemist André-Louis Debierne (14 July 1874, Paris, France – 31 August 1949, Paris, France) is the first scientist who discovered this periodic table element. Debierne managed to isolate actinium by exploring a pitchblende, i.e., remainders of uranium ore (uranium oxide, U3O8) from the experiments on radium carried out by the Nobel-winning chemists Marie Curie and Pierre Curie. 

According to the findings of the French chemist, Debierne, the newly-discovered substance named actinium shares the chemical properties of titanium and thorium. This discovery took place in 1899, while Debierne was trying to separate rare earth oxides. 

 

How Did Actinium Get Its Name?

Three years later, after Debierne discovered actinium, Friedrich Oskar Giesel ( 20 May 1852, Winzig, Germany – 13 November 1927, Braunschweig, Germany) discovered this element while conducting his scientific research, without knowing that it had already been discovered. His results showed similarities between actinium and lanthanum. In 1904, Giesel labeled the new element as “emanium”. 

Since there were two independent discoveries of the same chemical element, several other scientists compared Debierne and Giesel’s research. In the 1970s, the first Canadian female nuclear physicist and two German chemists (Harriet Brooks, Otto Hahn, and Otto Sackur) comprised the scientific research team that confirmed the chemical properties of the new substance and decided to keep its first name. In this way, Debierne holds the honor of being the first chemist to discover actinium. 

 

Where Can You Find Actinium?

Actinium can be found in microscopic traces in uranium or thorium ore. Only 0.15 mg of actinium can be found in a tone of pitchblende ore. Due to its scarcity, this chemical element is often produced in labs. Its production is costly and dangerous, so the application of actinium is limited to scientific, energetic, and medical uses, such as in nuclear reactors, radiation therapy, etc.

 

Nuclear Medicine (Radiation Therapy)

Nuclear medicine is a biology branch that uses small doses of radioactive substances to examine and treat malignant (cancerous) tumors. By implementing radiation therapy (or radiotherapy) in the treatments, nuclear medicine utilizes the high intensity of the radioactive beams to destroy malignant tumor cells. More specifically, actinium-255 (Ac-255) isotope with a half-life of 10 days is used in the treatment of cancer patients. This type of radiation therapy is typically performed via extremely short electromagnetic waves of high energy. 

These high-energy waves are produced in a special machine that radiates the beams precisely onto the tumorous lump formed on a particular tissue. The beams protrude the mutated neuron cell’s body and destroy the genetic material they carry. That’s how radiation therapy controls or completely stops the multiplication and growth of cancerous cells in the body. 

 

Spacecraft Power Systems

Since there are no gas stations for spacecraft in space, the production of neutrons is the only solution for fueling the vehicles that are on a mission of exploring the Solar System. 

Due to the high activity level of actinium, spacecraft power systems use the radioisotope power and neutron irradiation that is generated by the radioactive elements. When actinium (or any other radioactive element) breaks down, it generates heat that is used by these power systems as a source of energy.  

 

Nuclear Power Reactors

A nuclear power reactor is a machine that generates electricity by splitting the atoms of particular chemical elements apart and producing neutrons by a controlled nuclear reaction. That’s why radioactive elements are used as fuel.  

 

How Dangerous Is Actinium?

Actinium imposes enormous health hazards due to its intense radioactivity. Despite being used to cure cancer and heal the body’s tissues, healthy cells are also destroyed alongside tumorous cells during radiation therapy in cancer patients. The body reacts to the destruction of healthy cells due to radioactivity exposure by triggering:

• Hair loss;
• Nausea; 
• Vomiting;
• Fatigue;
• Open sores on the skin and in the mouth. 

Exposure to radiation can also lead to severe illnesses such as leukemia, stillbirths, lowered immunological defenses of the body, etc. 

 

Environmental Effects of Actinium

When radioactive waste is improperly discarded, it pollutes nature – the rivers, seas, oceans, forests – and the entire ecosystem. Spreading through the food chain and destroying the natural habitats of animals, birds, fish, and humans, radiation can lead to the complete destruction of various gene pools as well as the ecosystems on the planet.  

 

Actinium Isotopes

This chemical element has more than 25 isotopes, among which we could mention the following:

• Actinium-223 (232Th(d,7n)→227Pa(α)→223Ac) – With a half-life of 2.1 minutes, this isotope is used to produce fuel for nuclear weapons and nuclear reactors.
• Actinium-225 (232Th(n,γ)→233Th(β−)→233Pa(β−)→233U(α)→229Th(α)→225Ra(β−)→225Ac) – This actinium isotope has notable application in nuclear medicine, as a part of the treatment for cancer patients. Its half-life is 9.92 days. Actinium-255 undergoes alpha decay to francium-221 with a half-life of ten days. Its isotopes emit alpha particles that do not produce gamma rays. 
• Actinium-227 (235U(α)→231Th(β−)→231Pa(α)→227Ac) – The half-life of this purified actinium isotope is 21.77, which makes it one of the most stable actinium isotopes. It’s used for neutron production. Actinium-277 undergoes alpha decay to francium-223 with a half-life of 22.00 minutes.
• Actinium-228 (232Th(α)→228Ra(β−)→228Ac) – Apart from being used as a source of neutron production and an element of the radiation therapy of patients suffering from a malign tumor, this actinium isotope has no additional application. 
• Actinium-229 (228Ra(n,γ)→229Ra(β−)→229Ac) – With a half-life of 1.04 hours, this is one of the least stable isotopes of actinium with no significant commercial use. 
• Actinium-230 (232Th(d,α)→230Ac) is a neuron-rich isotope of actinium with a half-life of 122s.

Actinium-217 is the isotope of this radioactive chemical element with the shortest half-life of only 69ns.

 

 

Actinium Decay Products

The 4n+3 decay chain of uranium-235 comprises the following chemical elements: radium, radon, francium, lead, protactinium, thallium, thorium, bismuth, astatine, and actinium. All of these elements are found in uranium ores in varying quantities and are labeled as the “actinium series” or “actinium cascade”. These emit alpha-particles.

nuclide	historic name (short)	historic name (long)	decay mode	half-life   (a=year)	energy released, MeV	product of decay
251Cf			α	900.6 a	6.176	247Cm
247Cm			α	1.56·107 a	5.353	243Pu
243Pu			β−	4.95556 h	0.579	243Am
243Am			α	7388 a	5.439	239Np
239Np			β−	2.3565 d	0.723	239Pu
239Pu			α	2.41·104 a	5.244	235U
235U	AcU	Actin Uranium	α	7.04·108 a	4.678	231Th
231Th	UY	Uranium Y	β−	25.52 h	0.391	231Pa
231Pa	Pa	Protactinium	α	32760 a	5.150	227Ac
227Ac	Ac	Actinium	β− 98.62%   α 1.38%	21.772 a	0.045   5.042	227Th   223Fr
227Th	RdAc	Radio-actinium	α	18.68 d	6.147	223Ra
223Fr	AcK	Actinium K	β− 99.994%   α 0.006%	22.00 min	1.149   5.340	223Ra   219At
223Ra	AcX	Actinium X	α	11.43 d	5.979	219Rn
219At			α 97.00%   β− 3.00%	56 s	6.275   1.700	215Bi   219Rn
219Rn	An	Actinon,   Actinium Emanation	α	3.96 s	6.946	215Po
215Bi			β−	7.6 min	2.250	215Po
215Po	AcA	Actinium A	α 99.99977%   β− 0.00023%	1.781 ms	7.527   0.715	211Pb   215At
215At			α	0.1 ms	8.178	211Bi
211Pb	AcB	Actinium B	β−	36.1 min	1.367	211Bi
211Bi	AcC	Actinium C	α 99.724%   β− 0.276%	2.14 min	6.751   0.575	207Tl   211Po
211Po	AcC’	Actinium C’	α	516 ms	7.595	207Pb
207Tl	AcC”	Actinium C”	β−	4.77 min	1.418	207Pb
207Pb	AcD	Actinium D	.	stable	.	.

 

 

Chemical Compounds of Actinium

The list of chemical compounds of actinium includes:

• Actinium fluoride (AcF3);
• Actinium (III) oxide (Ac2O3);
• Uraninite (UO2);
• DOTA / Tetraxetan (C16H28N4O8);
• Actinium dihydride (AcH2);
• Actinium triiodide (AcI3).

 

5 Interesting Facts and Explanations

 

• The meaning behind the name of the chemical element actinium derives from the Greek word aktinos, meaning “beam” or “ray”. This refers to its property of glowing in the dark.
• Debierne managed to extract actinium from uranium ore by using ammonia. 
• Radiology analyzes and diagnoses physical anatomy changes, while nuclear medicine deals with molecular structures, cells, chemical processes, and interactions within a biological system. 

1. The family of actinides in the periodic table of elements is made up of actinium, thorium, protactinium, uranium, neptunium, plutonium, americium, curium, berkelium, californium, einsteinium, fermium, mendelevium, nobelium, and lawrencium.
2. The term gene pool refers to the collection of the entire genetic material of a given generation. People in a given country, the fish in a lake, or the animals of a particular rain forest are some examples of gene pools.